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Mechanistic Evaluation of the Ni(IPr)(2)−Catalyzed Cycloaddition of Alkynes and Nitriles to Afford Pyridines: Evidence for the Formation of a Key η(1)−Ni(IPr)(2)(RCN) Intermediate
A detailed mechanistic evaluation of the Ni(IPr)(2)-catalyzed [2+2+2]-cycloaddition of diynes and nitriles was 2 conducted. Through kinetic analysis of these reactions, observed regioselectivities of the products, and stoichiometric reactions, Ni(IPr)(2)-catalyzed cycloadditions of diynes and nitril...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4159214/ https://ncbi.nlm.nih.gov/pubmed/25214702 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400666k |
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