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A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

A one-pot procedure for the synthesis of [Cu(X)(NHC)] (X = Cl, Br, I) is reported. The reaction is applicable to a wide range of saturated and unsaturated NHC ligands, is scalable and proceeds under mild conditions using technical grade solvents in air.

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Santoro, Orlando, Collado, Alba, Slawin, Alexandra M. Z., Nolan, Steven P., Cazin, Catherine S. J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2013
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4155829/
https://ncbi.nlm.nih.gov/pubmed/24087835
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc45488f
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