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The iron-catalyzed construction of 2-aminopyrimidines from alkynenitriles and cyanamides()

Several cycloaddition catalysts and reagents were surveyed for their effectiveness toward cyclizing alkynenitriles with cyanamides. Catalytic amounts of FeI(2), (iPr)PDAI and Zn were found to effectively catalyze the [2+2+2] cycloaddition of a variety of cyanamides and alkynenitriles to afford bicyc...

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Detalhes bibliográficos
Main Authors: Lane, Timothy K., Nguyen, Minh H., D'Souza, Brendan R., Spahn, Nathan A., Louie, Janis
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4144345/
https://ncbi.nlm.nih.gov/pubmed/23877441
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc44422h
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