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C–H-Functionalization logic guides the synthesis of a carbacyclopamine analog

The chemical synthesis of carbacyclopamine analog 2, a cyclopamine analog with an all-carbon E-ring, is reported. The use of C–H-functionalization logic and further metal-catalyzed transformations allows for a concise entry to this new class of acid-stable cyclopamine analogs.

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Bibliografiska uppgifter
Huvudupphovsmän: Rabe, Sebastian, Moschner, Johann, Bantzi, Marina, Heretsch, Philipp, Giannis, Athanassios
Materialtyp: Artigo
Språk:Inglês
Publicerad: Beilstein-Institut 2014
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142839/
https://ncbi.nlm.nih.gov/pubmed/25161712
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.161
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