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[3+2] Photooxygenation of aryl cylopropanes via visible light photocatalysis

We report that Ru(bpz)(3)(2+) is an excellent sensitizer for the photooxygenation of aryl cyclopropanes upon irradiation with visible light. The effectiveness of this photocatalyst enables the synthesis of a range of five-membered endoperoxides in excellent yield with quite low (0.5 mol%) catalyst l...

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Autors principals: Lu, Zhan, Parrish, Jonathan D., Yoon, Tehshik P.
Format: Artigo
Idioma:Inglês
Publicat: 2014
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4142714/
https://ncbi.nlm.nih.gov/pubmed/25170179
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2014.02.045
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