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Structural Change of the Mn Cluster during the S(2)→S(3) State Transition of the Oxygen-Evolving Complex of Photosystem II. Does It Reflect the Onset of Water/Substrate Oxidation? Determination by Mn X-ray Absorption Spectroscopy
The oxygen-evolving complex of Photosystem II in plants and cyanobacteria catalyzes the oxidation of two water molecules to one molecule of dioxygen. A tetranuclear Mn complex is believed to cycle through five intermediate states (S(0)–S(4)) to couple the four-electron oxidation of water with the on...
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| Hauptverfasser: | , , , , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2000
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4138610/ https://ncbi.nlm.nih.gov/pubmed/25152534 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja992501u |
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