Proton transfers are key elementary steps in ethylene polymerization on isolated chromium(III) silicates

Mononuclear Cr(III) surface sites were synthesized from grafting [Cr(OSi(O(t)Bu)(3))(3)(tetrahydrofurano)(2)] on silica partially dehydroxylated at 700 °C, followed by a thermal treatment under vacuum, and characterized by infrared, ultraviolet-visible, electron paramagnetic resonance (EPR), and X-r...

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Detalhes bibliográficos
Main Authors: Delley, Murielle F., Núñez-Zarur, Francisco, Conley, Matthew P., Comas-Vives, Aleix, Siddiqi, Georges, Norsic, Sébastien, Monteil, Vincent, Safonova, Olga V., Copéret, Christophe
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2014
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4136591/
https://ncbi.nlm.nih.gov/pubmed/25002479
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1405314111
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