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Metal-free transfer hydrogenation of olefins via dehydrocoupling catalysis
A major advance in main-group chemistry in recent years has been the emergence of the reactivity of main-group species that mimics that of transition metal complexes. In this report, the Lewis acidic phosphonium salt [(C(6)F(5))(3)PF][B(C(6)F(5))(4)] 1 is shown to catalyze the dehydrocoupling of sil...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4121813/ https://ncbi.nlm.nih.gov/pubmed/25002489 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1407484111 |
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