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Crystal structures of (μ(2)-η(2),η(2)-4-hydroxybut-2-yn-1-yl 2-bromo-2-methylpropanoate-κ(4) C (2),C (3):C (2),C (3))bis[tricarbonylcobalt(II)](Co—Co) and [μ(2)-η(2),η(2)-but-2-yne-1,4-diyl bis(2-bromo-2-methylpropanoate)-κ(4) C (2),C (3):C (2),C (3)]bis[tricarbonylcobalt(II)](Co—Co)

The title compounds, [Co(2)(C(8)H(11)BrO(3))(CO)(6)], (1), and [Co(2)(C(12)H(16)Br(2)O(4))(CO)(6)], (2), result from the replacement of two carbonyl ligands from dicobalt octacarbonyl by the alkynes 4-hydroxybut-2-ynyl 2-bromo-2-methylpropanoate and but-2-yne-1,4-diyl bis(2-bromo-2-methylprop...

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Detalhes bibliográficos
Main Authors:	McAdam, C. John, Moratti, Stephen C., Robinson, Brian H., Simpson, Jim, Stanley, Roderick G.
Formato:	Artigo
Idioma:	Inglês
Publicado em:	International Union of Crystallography 2014
Assuntos:	Research Communications
Acesso em linha:	https://ncbi.nlm.nih.gov/pmc/articles/PMC4120535/ https://ncbi.nlm.nih.gov/pubmed/25161495 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536814009659
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Crystal structures of (μ(2)-η(2),η(2)-4-hydroxybut-2-yn-1-yl 2-bromo-2-methylpropanoate-κ(4) C (2),C (3):C (2),C (3))bis[tricarbonylcobalt(II)](Co—Co) and [μ(2)-η(2),η(2)-but-2-yne-1,4-diyl bis(2-bromo-2-methyl­propanoate)-κ(4) C (2),C (3):C (2),C (3)]bis[tricarbonylcobalt(II)](Co—Co)

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Crystal structures of (μ(2)-η(2),η(2)-4-hydroxybut-2-yn-1-yl 2-bromo-2-methylpropanoate-κ(4) C (2),C (3):C (2),C (3))bis[tricarbonylcobalt(II)](Co—Co) and [μ(2)-η(2),η(2)-but-2-yne-1,4-diyl bis(2-bromo-2-methylpropanoate)-κ(4) C (2),C (3):C (2),C (3)]bis[tricarbonylcobalt(II)](Co—Co)