Chain-End-Functionalized Polyphosphazenes via a One-Pot Phosphine-Mediated Living Polymerization

A simple polymerization of trichlorophosphoranimine (Cl(3)P = N−SiMe(3)) mediated by functionalized triphenylphosphines is presented. In situ initiator formation and the subsequent polymerization progress are investigated by (31)P NMR spectroscopy, demonstrating a living cationic polymerization mech...

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Bibliografiske detaljer
Main Authors: Wilfert, Sandra, Henke, Helena, Schoefberger, Wolfgang, Brüggemann, Oliver, Teasdale, Ian
Format: Artigo
Sprog:Inglês
Udgivet: BlackWell Publishing Ltd 2014
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4115175/
https://ncbi.nlm.nih.gov/pubmed/24700544
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/marc.201400114
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