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Arenium ions are not obligatory intermediates in electrophilic aromatic substitution
Our computational and experimental investigation of the reaction of anisole with Cl(2) in nonpolar CCl(4) solution challenges two fundamental tenets of the traditional S(E)Ar (arenium ion) mechanism of aromatic electrophilic substitution. Instead of this direct substitution process, the alternative...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2014
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4104905/ https://ncbi.nlm.nih.gov/pubmed/24972792 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1405065111 |
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