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Arenium ions are not obligatory intermediates in electrophilic aromatic substitution

Our computational and experimental investigation of the reaction of anisole with Cl(2) in nonpolar CCl(4) solution challenges two fundamental tenets of the traditional S(E)Ar (arenium ion) mechanism of aromatic electrophilic substitution. Instead of this direct substitution process, the alternative...

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Détails bibliographiques
Auteurs principaux: Galabov, Boris, Koleva, Gergana, Simova, Svetlana, Hadjieva, Boriana, Schaefer, Henry F., Schleyer, Paul von Ragué
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 2014
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4104905/
https://ncbi.nlm.nih.gov/pubmed/24972792
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1405065111
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