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Terminal Olefins to Linear α,β-Unsaturated Ketones: Pd (II)/Hypervalent Iodine Co-Catalyzed Wacker-Dehydrogenation
Development of a mild (35°C, no Brönsted acids) tandem Wacker-dehydrogenation of terminal olefins was accomplished using palladium(II) and hypervalent iodine co-catalysis. The reaction affords linear aryl and alkyl α,β- unsaturated ketones directly from readily available terminal olefins in good yie...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4084756/ https://ncbi.nlm.nih.gov/pubmed/23672479 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402651q |
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