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Site-selective covalent functionalization at interior carbon atoms and on the rim of circumtrindene, a C(36)H(12) open geodesic polyarene

Circumtrindene (6, C(36)H(12)), one of the largest open geodesic polyarenes ever reported, exhibits fullerene-like reactivity at its interior carbon atoms, whereas its edge carbons react like those of planar polycyclic aromatic hydrocarbons (PAHs). The Bingel–Hirsch and Prato reactions – two traditi...

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Detalhes bibliográficos
Main Authors: Cho, Hee Yeon, Ansems, Ronald B M, Scott, Lawrence T
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4077463/
https://ncbi.nlm.nih.gov/pubmed/24991245
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.94
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