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Volcano plots in hydrogen electrocatalysis – uses and abuses

Sabatier’s principle suggests, that for hydrogen evolution a plot of the rate constant versus the hydrogen adsorption energy should result in a volcano, and several such plots have been presented in the literature. A thorough examination of the data shows, that there is no volcano once the oxide-cov...

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Detalhes bibliográficos
Main Authors: Quaino, Paola, Juarez, Fernanda, Santos, Elizabeth, Schmickler, Wolfgang
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4077405/
https://ncbi.nlm.nih.gov/pubmed/24991521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjnano.5.96
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