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Geometric consequences of electron delocalization for adenine tautomers in aqueous solution

Geometric consequences of electron delocalization were studied for all possible adenine tautomers in aqueous solution by means of ab initio methods {PCM(water)//DFT(B3LYP)/6-311+G(d,p)} and compared to those in the gas phase {DFT(B3LYP)/6-311+G(d,p)}. To measure the consequences of any type of reson...

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Main Authors: Raczyńska, Ewa D., Makowski, Mariusz
Formato: Artigo
Idioma:Inglês
Publicado: Springer Berlin Heidelberg 2014
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4072068/
https://ncbi.nlm.nih.gov/pubmed/24842324
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00894-014-2234-4
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