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Catalysis of electron transfer during activation of O(2) by the flavoprotein glucose oxidase

Two prototropic forms of glucose oxidase undergo aerobic oxidation reactions that convert FADH(−) to FAD and form H(2)O(2) as a product. Limiting rate constants of k(cat)/K(M)(O(2)) = (5.7 ± 1.8) × 10(2) M(−1)⋅s(−1) and k(cat)/K(M)(O(2)) = (1.5 ± 0.3) × 10(6) M(−1)⋅s(−1) are observed at high and low...

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Detalhes bibliográficos
Main Authors: Roth, Justine P., Klinman, Judith P.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2003
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC404145/
https://ncbi.nlm.nih.gov/pubmed/12506204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.252644599
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