Preparation of Diversely Substituted Triarylmethyl Radicals by the Quenching of Tris(2,3,5,6-tetrathiaaryl)methyl Cations with C-, N-, P-, and S-Nucleophiles

C-, N-, P-, and S-nucleophiles reacted with symmetrical tris(2,3,5,6-tetrathiaaryl)methyl cations, generated from the corresponding triarylmethanols by strong acids, to give a variety of asymmetrical monosubstituted persistent triaryl-methyl (TAM) radicals as the major products. The only byproducts...

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Main Authors: Tormyshev, Victor M., Rogozhnikova, Olga Yu., Bowman, Michael K., Trukhin, Dmitry V., Troitskaya, Tatiana I., Vasiliev, Vladimir G., Shundrin, Leonid A., Halpern, Howard J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4038673/
https://ncbi.nlm.nih.gov/pubmed/24883040
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201301161
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