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Chemo- and Regioselective C(sp(3))–H Arylation of Unactivated Allylarenes via a Deprotonative Cross-coupling Process
The combination of aryl bromides, allylbenzene, base and a palladium catalyst usually results in a Heck reaction. Herein we combine these same reagents, but override the Heck pathway by employing a strong base. In the presence of LiN(SiMe(3))(2), allylbenzene derivatives undergo reversible deprotona...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4038169/ https://ncbi.nlm.nih.gov/pubmed/24574070 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201309084 |
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