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Tri-μ-chlorido-bis­[(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III)] hexa­fluorido­phosphate from synchrotron radiation

In the title complex salt, [{(η(5)-C(5)Me(5))Rh}(2)(μ-Cl)(3)]PF(6), the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C(5)Me(5))RhCl(3) ‘piano-stool’ units by bridging of the three choride ligand ‘legs’. The crystal structure shows several close H⋯F contacts betwee...

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Detalhes bibliográficos
Main Authors: Ezzedinloo, Lida, Shrestha, Sumi, Bhadbhade, Mohan, Colbran, Stephen
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4029212/
https://ncbi.nlm.nih.gov/pubmed/24855466
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536813032480
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