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Revisiting H(2)O Nucleation around Au(+) and Hg(2+): The Peculiar “Pseudo-Soft” Character of the Gold Cation

[Image: see text] In this contribution, we propose a deeper understanding of the electronic effects affecting the nucleation of water around the Au(+) and Hg(2+) metal cations using quantum chemistry. To do so, and in order to go beyond usual energetical studies, we make extensive use of state of th...

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Detalhes bibliográficos
Main Authors: Chaudret, Robin, Contreras-Garcia, Julia, Delcey, Mickaël, Parisel, Olivier, Yang, Weitao, Piquemal, Jean-Philip
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4025583/
https://ncbi.nlm.nih.gov/pubmed/24860276
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ct4006135
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