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N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C–C and C–N Cross-Couplings

[Image: see text] A series of phosphine-ligated palladium precatalysts based on N-methyl- and N-phenyl-2-aminobiphenyl have been developed. Substitution at the nitrogen center prevents the presence of traces of aminobiphenyls that contain a free −NH(2) group from contaminating cross-coupling product...

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Detalhes bibliográficos
Main Authors: Bruno, Nicholas C., Niljianskul, Nootaree, Buchwald, Stephen L.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4017611/
https://ncbi.nlm.nih.gov/pubmed/24724692
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500355k
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