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Aryl C—H···Cl(–) Hydrogen Bonding in a Fluorescent Anion Sensor

A new phenyl-acetylene receptor containing a carbonaceous hydrogen bond donor activates anion binding in conjunction with two stabilizing ureas. The unusual CH···Cl(–) hydrogen bond is apparent in solution by large (1)H NMR chemical shifts and by a short, linear contact in the solid state.

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Autori principali: Tresca, Blakely W., Zakharov, Lev N., Carroll, Calden N., Johnson, Darren W., Haley, Michael M.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4012615/
https://ncbi.nlm.nih.gov/pubmed/23843050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3cc44574g
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