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Synthesis and Transformations of 5-Chloro-2,2′-Dipyrrins and Their Boron Complexes, 8-Chloro-BODIPYs()

Symmetric dipyrrylketones 1a,b were synthesized in two steps from the corresponding α-free pyrroles, by reaction with thiophosgene followed by oxidative hydrolysis under basic conditions. The dipyrrylketones produced the corresponding 5-chloro-dipyrrinium salts or 5-ethoxy-dipyrrins on reaction with...

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Bibliografische gegevens
Hoofdauteurs: Wang, Haijun, Vicente, M. Graça H., Fronczek, Frank R., Smith, Kevin M.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2014
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4012389/
https://ncbi.nlm.nih.gov/pubmed/24616111
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201304310
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