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Single molecule fluorescence probes dynamics of barrier crossing

Kramers developed the theory on how chemical reaction rates are influenced by the viscosity of the medium(1,2). At the viscosity of water, the kinetics of unimolecular reactions are described by diffusion of a Brownian particle over a free-energy barrier separating reactants and products. For reacti...

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Bibliografiska uppgifter
Huvudupphovsmän: Chung, Hoi Sung, Eaton, William A.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2013
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4009947/
https://ncbi.nlm.nih.gov/pubmed/24153185
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nature12649
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