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Oxacycle Synthesis via Intramolecular Reaction of Carbanions and Peroxides
[Image: see text] The intramolecular reaction of dialkyl peroxides with carbanions, generated via chemoselective metal-heteroatom exchange or deprotonation, provides a new approach to cyclic ethers. Applied in tandem with C–C bond formation, the strategy enables a one-step annelation to form oxaospi...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
American Chemical
Society
2014
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| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4004269/ https://ncbi.nlm.nih.gov/pubmed/24702123 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja5026276 |
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