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Group-assisted purification (GAP) chemistry for the synthesis of Velcade via asymmetric borylation of N-phosphinylimines

A new approach to the anticancer drug Velcade was developed by performing asymmetric borylation of an imine anchored with a chiral N-phosphinyl auxiliary. Throughout the 7-step synthesis, especially in the imine’s synthesis and in the asymmetric borylation reactions, operations and work-up were cond...

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Detalhes bibliográficos
Main Authors: Xie, Jian-bo, Luo, Jian, Winn, Timothy R, Cordes, David B, Li, Guigen
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3999766/
https://ncbi.nlm.nih.gov/pubmed/24778728
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.69
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