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μ-Oxido-bis­[hydridotris(tri­methyl­phosphane-κP)iridium(III)](Ir—Ir) bis­(tetra­fluorido­borate) dihydrate

The title compound, [Ir(2)H(2)O(C(3)H(9)P)(6)](BF(4))(2)·2H(2)O, was isolated from the reaction between [Ir(COD)(PMe(3))(3)]BF(4) and H(2) in water (COD is cyclo­octa-1,5-diene). The asymmetric unit consists of one Ir(III) atom bonded to three PMe(3) groups, one hydride ligand and half an oxide liga...

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Detalhes bibliográficos
Main Authors: Merola, Joseph, Husebo, Trang Le
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3998581/
https://ncbi.nlm.nih.gov/pubmed/24826089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S160053681400453X
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