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Guest-Adaptable and Water-Stable Peptide-Based Porous Materials by Imidazolate Side Chain Control**
The peptide-based porous 3D framework, ZnCar, has been synthesized from Zn(2+) and the natural dipeptide carnosine (β-alanyl-L-histidine). Unlike previous extended peptide networks, the imidazole side chain of the histidine residue is deprotonated to afford Zn–imidazolate chains, with bonding simila...
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Main Authors: | , , , , , , , , , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Wiley-VCH Verlag GmbH & Co
2014
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3995008/ https://ncbi.nlm.nih.gov/pubmed/24302659 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201307074 |
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