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Beyond the Roche Ester: A New Approach to Polypropionate Stereotriad Synthesis
[Image: see text] An efficient, step-economical, and scalable approach to the synthesis of polypropionate stereotriads has been developed. Either 2-butyne or propyne is subjected to rhodium-catalyzed silylformylation and in situ crotylation of the resulting aldehydes. Tamao oxidation under either “s...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2014
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3993613/ https://ncbi.nlm.nih.gov/pubmed/24502345 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol500051e |
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