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Internuclear (31)P-(51)V Distance Measurements in Polyoxoanionic Solids Using REAPDOR NMR Spectroscopy

We report the first results establishing REAPDOR experiments for distance measurements between a spin-1/2 ((31)P) and spin-7/2 ((51)V) pair in a series of vanadium-substituted polyoxoanionic solids from the Keggin and Wells-Dawson families. We have quantitatively measured (31)P-(51)V distances in mo...

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Detalhes bibliográficos
Main Authors: Huang, Wenlin, Vega, Alexander J., Gullion, Terry, Polenova, Tatyana
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985602/
https://ncbi.nlm.nih.gov/pubmed/17918932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja073170l
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