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SET-Induced Biaryl Cross-Coupling: An S(RN)1 Reaction

[Image: see text] The SET-induced biaryl cross-coupling reaction is established as the first example of a Grignard S(RN)1 reaction. The reaction is examined within the mechanistic framework of dissociative electron transfer in the presence of a Lewis acid. DFT calculations show that the reaction pro...

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Bibliographic Details
Main Authors: Haines, Brandon E., Wiest, Olaf
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3985438/
https://ncbi.nlm.nih.gov/pubmed/24564385
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo500222d
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