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Solid-phase synthesis of chiral 3,4-diazaphospholanes and their application to catalytic asymmetric allylic alkylation

Functionalized chiral diazaphospholanes ligate to a variety of transition metals, yielding chiral, catalytically active, metal complexes. Previous work has established that amino acid derivatization of the carboxyl groups of (R,R)-N,N′-phthaloyl-2,3-(2-carboxyphenyl)-phenyl-3,4-diazaphospholane (1)...

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Autores principales: Landis, Clark R., Clark, Thomas P.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2004
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC397399/
https://ncbi.nlm.nih.gov/pubmed/14985503
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0307572100
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