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Nonenzymatic Synthesis of the P-Cluster in the Nitrogenase MoFe Protein: Evidence of the Involvement of All-Ferrous [Fe(4)S(4)](0) Intermediates

[Image: see text] The P-cluster in the nitrogenase MoFe protein is a [Fe(8)S(7)] cluster and represents the most complex FeS cluster found in Nature. To date, the exact mechanism of the in vivo synthesis of the P-cluster remains unclear. What is known is that the precursor to the P-cluster is a pair...

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Detalhes bibliográficos
Main Authors: Rupnik, Kresimir, Lee, Chi Chung, Wiig, Jared A., Hu, Yilin, Ribbe, Markus W., Hales, Brian J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3970913/
https://ncbi.nlm.nih.gov/pubmed/24520862
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi401699u
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