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Dichlorination of (HDDA-Generated) Benzynes and a Protocol for Interrogating the Kinetic Order of Bimolecular Aryne Trapping Reactions
[Image: see text] The efficient dichlorination of benzynes prepared by the hexadehydro-Diels–Alder (HDDA) reaction is reported. Cycloisomerization of a triyne substrate in the presence of dilithium tetrachlorocuprate is shown to provide dichlorinated products A by capture of the benzyne intermediate...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2013
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3955733/ https://ncbi.nlm.nih.gov/pubmed/24329102 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol403258c |
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