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Synthesis and stereochemical assignments of diastereomeric Ni(II) complexes of glycine Schiff base with (R)-2-(N-{2-[N-alkyl-N-(1-phenylethyl)amino]acetyl}amino)benzophenone; a case of configurationally stable stereogenic nitrogen

A family of chiral ligands derived from α-phenylethylamine and 2-aminobenzophenone were prepared by alkylation of the nitrogen atom. Upon reaction with glycine and a Ni(II) salt, these ligands were transformed into diastereomeric complexes, as a result of the configurational stability of the stereog...

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Библиографические подробности
Главные авторы: Moriwaki, Hiroki, Resch, Daniel, Li, Hengguang, Ojima, Iwao, Takeda, Ryosuke, Aceña, José Luis, Soloshonok, Vadim A
Формат: Artigo
Язык:Inglês
Опубликовано: Beilstein-Institut 2014
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3943998/
https://ncbi.nlm.nih.gov/pubmed/24605164
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.41
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