Self-assembly of metallosupramolecular rhombi from chiral concave 9,9’-spirobifluorene-derived bis(pyridine) ligands

Two new 9,9’-spirobifluorene-based bis(4-pyridines) were synthesised in enantiopure and one also in racemic form. These ligands act as concave templates and form metallosupramolecular [(dppp)(2)M(2)L(2)] rhombi with cis-protected [(dppp)Pd](2+) and [(dppp)Pt](2+) ions. The self-assembly process of t...

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Hauptverfasser: Hovorka, Rainer, Hytteballe, Sophie, Piehler, Torsten, Meyer-Eppler, Georg, Topić, Filip, Rissanen, Kari, Engeser, Marianne, Lützen, Arne
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2014
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Full Research Paper
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3943293/
https://ncbi.nlm.nih.gov/pubmed/24605163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.10.40
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