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A Computational Study of the Copper(II) Catalyzed Enantioselective Intramolecular Aminooxygenation of Alkenes

The origin of enantioselectivity in the [Cu(R,R)-Ph-box](OTf)(2)-catalyzed intramolecular aminooxygenation of N-sulfonyl-2-allylanilines and 4-pentenylsulfonamides to afford chiral indolines and pyrrolidines, respectively, was investigated using Density Functional Theory (DFT) calculations. The pyrr...

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Hlavní autoři: Belding, Lee, Chemler, Sherry, Dudding, Travis
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3940240/
https://ncbi.nlm.nih.gov/pubmed/24032369
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401665n
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