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Turnover-Dependent Inactivation of the Nitrogenase MoFe-Protein at High pH

[Image: see text] Proton uptake accompanies the reduction of all known substrates by nitrogenase. As a consequence, a higher pH should limit the availability of protons as a substrate essential for turnover, thereby increasing the proportion of more highly reduced forms of the enzyme for further stu...

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Detalhes bibliográficos
Main Authors: Yang, Kun-Yun, Haynes, Chad A., Spatzal, Thomas, Rees, Douglas C., Howard, James B.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2013
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3932303/
https://ncbi.nlm.nih.gov/pubmed/24392967
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi4014769
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