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Toward a synthesis of hirsutellone B by the concept of double cyclization
This account describes a strategy for directly forming three of the six rings found in the polyketide natural product hirsutellone B via a novel cyclization cascade. The key step in our approach comprises two transformations: a large-ring forming, nucleophilic capture of a transient acyl ketene and...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2013
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3920480/ https://ncbi.nlm.nih.gov/pubmed/24032341 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo401799f |
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