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Influence of Side Chain Conformation and Configuration on Glycosyl Donor Reactivity and Selectivity as Illustrated by Sialic Acid Donors Epimeric at the 7-Position
Two N-acetyl 4O,5N-oxazolidine-protected sialyl thioglycosides epimeric at the 7-position have been synthesized and their reactivity and stereoselectivity in glycosylation reactions compared. It is demonstrated that the natural 7S-donor is both more reactive and more α-selective than the unnatural 7...
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| Glavni autori: | , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2013
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3917720/ https://ncbi.nlm.nih.gov/pubmed/24261615 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410683y |
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