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Influence of Side Chain Conformation and Configuration on Glycosyl Donor Reactivity and Selectivity as Illustrated by Sialic Acid Donors Epimeric at the 7-Position

Two N-acetyl 4O,5N-oxazolidine-protected sialyl thioglycosides epimeric at the 7-position have been synthesized and their reactivity and stereoselectivity in glycosylation reactions compared. It is demonstrated that the natural 7S-donor is both more reactive and more α-selective than the unnatural 7...

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Bibliografski detalji
Glavni autori: Kancharla, Pavan K., Crich*, David
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3917720/
https://ncbi.nlm.nih.gov/pubmed/24261615
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410683y
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