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Chemical Excision of Tetrahedral FeSe(2) Chains from the Superconductor FeSe: Synthesis, Crystal Structure, and Magnetism of Fe(3)Se(4)(en)(2)

Fragments of the superconducting FeSe layer, FeSe(2) tetrahedral chains, were stabilized in the crystal structure of a new mixed-valent compound Fe(3)Se(4)(en)(2) (en = ethylenediamine) synthesized from elemental Fe and Se. The FeSe(2) chains are separated from each other by means of Fe(en)(2) linke...

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Detalhes bibliográficos
Main Authors: Pak, Chongin, Kamali, Saeed, Pham, Joyce, Lee, Kathleen, Greenfield, Joshua T., Kovnir, Kirill
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3913537/
https://ncbi.nlm.nih.gov/pubmed/24299423
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja410820u
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