Driving force and nucleophilicity in S(N)2 displacements
The free energies of activation for reaction of six anionic nucleophiles with methyl iodide in dimethylformamide correlate linearly with the overall heats of reaction in the gas phase. The result indicates that nucleophilicity in this S(N)2 displacement reaction is dominated by electron affinity and...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Autor principal: | |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
1985
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC390900/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593634/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.82.24.8288 |
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