Stereochemical course of the reaction catalyzed by the pyridoxal phosphate-dependent enzyme 1-aminocyclopropane-1-carboxylate synthase.

(+/-)-S-adenosyl-DL-(3R*,4S*)-[3,4-2H2]-methionine [a 1:1 mixture of (3R,4S) and (3S,4R)] and (+/-)-S-adenosyl-DL-(3R*,4R*)-[3,4-2H2]methionine [a 1:1 mixture of (3R,4R) and (3S,4S)] were synthesized from (Z)- and (E)-[1,2-2H2]ethene, respectively. Key steps in the synthesis were the antiperiplanar...

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Detalhes bibliográficos
Main Authors: Ramalingam, K, Lee, K M, Woodard, R W, Bleecker, A B, Kende, H
Formato: Artigo
Idioma:Inglês
Publicado em: 1985
Assuntos:
Research Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC390861/
https://ncbi.nlm.nih.gov/pubmed/3865199
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