Stereochemical course of the reaction catalyzed by the pyridoxal phosphate-dependent enzyme 1-aminocyclopropane-1-carboxylate synthase.

(+/-)-S-adenosyl-DL-(3R*,4S*)-[3,4-2H2]-methionine [a 1:1 mixture of (3R,4S) and (3S,4R)] and (+/-)-S-adenosyl-DL-(3R*,4R*)-[3,4-2H2]methionine [a 1:1 mixture of (3R,4R) and (3S,4S)] were synthesized from (Z)- and (E)-[1,2-2H2]ethene, respectively. Key steps in the synthesis were the antiperiplanar...

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Enregistré dans:
Détails bibliographiques
Publié dans:Proc Natl Acad Sci U S A
Auteurs principaux: Ramalingam, K, Lee, K M, Woodard, R W, Bleecker, A B, Kende, H
Format: Artigo
Langue:Inglês
Publié: National Academy of Sciences 1985
Sujets:
Research Article
Accès en ligne:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC390861/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/3865199/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.82.23.7820
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