NHCs Catalyzed Hydrophosphonylation of α-Ketoesters and α-Trifluoromethyl Ketones

N-Heterocyclic carbenes catalyzed hydrophosphonylation reaction of α-ketoesters and α-trifluoromethyl ketones was developed. Under the catalysis of 10 mol% IPr, α-ketoesters or α-trifluoromethyl ketones reacted with dialkyl phosphites to provide quaternary α-hydroxyphosphonates in good to excellent...

Täydet tiedot

Tallennettuna:
Bibliografiset tiedot
Päätekijät: He, Lin, Cai, Zhi-Hua, Pian, Ji-Xin, Du, Guang-Fen
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: Hindawi Publishing Corporation 2013
Aiheet:
Research Article
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC3893873/
https://ncbi.nlm.nih.gov/pubmed/24489517
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1155/2013/890187
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