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The Absolute Configuration of Natural (-)-Stercobilin and Other Urobilinoid Compounds
Chromic acid degradation of natural (-)-stercobilin (1) yields 2(R)-methyl-3(R)-ethylsuccinimide (+2), whereby the absolute configuration of 1 at the chiral centers C-1, C-2, C-7, and C-8 is established. The substituted oxo-tetrahydrodipyrromethane precursor, 5, for the total synthesis of (-)-sterco...
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| Publié dans: | Proc Natl Acad Sci U S A |
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| Auteurs principaux: | , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
National Academy of Sciences
1971
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC389370/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/5289373/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.68.9.2141 |
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