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Photolabile Amphiphiles with Fluorogenic Thioxanthone-Dithiane Functionality: Synthesis and Photoinduced Fragmentation in Micelles

Novel photolabile amphiphiles containing thioxanthone-based fluorogenic caging groups are developed. Photoinduced fragmentation in dithiane-thioxanthone adducts was demonstrated to occur with 100% quantum efficiency at λ ~ 320 nm and more than 50% at λ ~ 360 nm. A plausible mechanism involves homoly...

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Detalhes bibliográficos
Main Authors: Ezhov, Roman N., Rozhkov, Vladimir V., Majjigapu, Janaki R. R., Kutateladze, Andrei G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3891307/
https://ncbi.nlm.nih.gov/pubmed/24436724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/17415990802027289
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