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[meso-5,10,15,20-Tetra­kis(3-methyl­thio­phen-2-yl)porphyrinato-κ(4) N,N′,N′′,N′′′]nickel(II) benzene hemisolvate

In the title compound, [Ni(C(40)H(28)N(4)S(4))]·0.5C(6)H(6), the Ni(II) atom is in a square-planar geometry defined by four pyrrole N atoms. There is considerable buckling in the porphyrin ring with the dihedral angles between the N(4) donor set and the pyrrole rings being in the range 16.24 (5)–22....

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Hlavní autoři: Prasath, R., Bhavana, P., Gupta, Sushil K., Butcher, Ray J.
Médium: Artigo
Jazyk:Inglês
Vydáno: International Union of Crystallography 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3884990/
https://ncbi.nlm.nih.gov/pubmed/24454165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S1600536813030468
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