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The Cation Radicals of Free Base and Zinc Bacteriochlorin, Bacteriochlorophyll, and Bacteriopheophytin

One-electron oxidation of zinc tetraphenylbacteriochlorin and its metal-free base yielded stable cation radicals. Electron spin resonance hyperfine splittings were assigned by selective deuterations. These results indicate that the protons of the saturated rings of the bacteriochlorins carry large s...

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Bibliographic Details
Published in:Proc Natl Acad Sci U S A
Main Authors: Fajer, J., Borg, D. C., Forman, A., Felton, R. H., Dolphin, D., Vegh, L.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 1974
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Online Access:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC388144/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16592150/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.71.3.994
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