Persistent confusion of total entropy and chemical system entropy in chemical thermodynamics.
The change in free energy with temperature at constant pressure of a chemical reaction is determined by the sum (dS) of changes in entropy of the system of reagents, dS(i), and the additional entropy change of the surroundings, dS(H), that results from the enthalpy change, W. A faulty identification...
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| Publicado en: | Proc Natl Acad Sci U S A |
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| Autor Principal: | |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
National Academy of Sciences
1996
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| Acceso en liña: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC38764/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/8755493/ https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.93.15.7452 |
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