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Synthetic Approaches to (smif)(2)Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) Reveal Redox Non-Innocence and C-C Bond-Formation

Attempted syntheses of (smif)(2)Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) based on metatheses of TiCl(n)L(m) (n = 2–4) with M(smif) (M = Li, Na), in the presence of a reducing agent (Na/Hg) when necessary, failed, but several apparent Ti(II) species were identified by X-ray crystallography and multi...

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Bibliografische gegevens
Hoofdauteurs: Frazier, Brenda A., Wolczanski, Peter T., Keresztes, Ivan, DeBeer, Serena, Lobkovsky, Emil B., Pierpont, Aaron W., Cundari, Thomas R.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3872169/
https://ncbi.nlm.nih.gov/pubmed/22830452
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic300590t
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